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Disinfection workshop summary
Weighing the risks and benefits of wet-weather disinfection
Presented at The Rosamond Gifford Zoo, Syracuse, NY
October 15, 2002
 

3. Total chlorine residual toxicity program

Presenter: Guy Apicella

Topic: Total chlorine residual toxicity program

Mr. Apicella described a project performed in New York City where acute and chronic toxicity testing was performed at fourteen wastewater treatment plants. Unchlorinated, chlorinated and dechlorinated effluents were studied. Exposure duration effects relevant to CSO discharges were evaluated.

  • Organism response to dechlorinated effluent is similar to unchlorinated effluent
  • 48-hr LC50 TRC was 0.3 to 0.6 mg/L for most sensitive species (mysid shrimp)
  • 6-hr LC50 TRC was 0.9 mg/L (typical exposure to CSO)
  • TRC decay in receiving water results in a substantial reduction factor in addition to dilution.


 
NYSDEC water quality standards for total residual chlorine
Water use / class Aquatic protection Freshwater (µg/L) Marine water (µg/L)
Fish propagation (A, B, C, SA, SB, SC, I) Chronic 5.0 7.5
Fish survival (D, SD) Acute 19.0 13.0

Acute toxicity at fourteen NYC water pollution control plants, unchlorinated effluent
Acute toxicity at fourteen NYC water pollution control plants, unchlorinated effluent


Acute toxicity at fourteen NYC water pollution control plants, chlorinated effluent
Acute toxicity at fourteen NYC water pollution control plants, chlorinated effluent


 
Mysid 48-hr LC50 vs TRC, all fourteen WPCPs 1989-1993   Effect of exposure duration mysid shrimp toxicity


NYSDEC's interim guidance for application of chlorine standard
Plant MA7CD10 dilution ranges SPDES effluent limit (µg/L)
80:1 2000
> 30:1 <= 80:1 500
<= 30:1 Dechlorination
Alt. disinfection
No disinfection

Presenter: Steven Freedman, Vice President, Brown and Caldwell

Augusta and Rockland ME CSO chlorination-dechlorination installations

Rockland, Maine facility
Rockland, Maine facility

Mr. Freedman presented bacteria reduction and effluent chlorine residuals from two CSO treatment facilities in Maine employing high-rate chlorination-dechlorination.

Presenter: Adam Zabinski, Deputy Commissioner, Westchester County Department of Environmental Facilities

Topic: Yonkers NY CSO Chlorination Installations

Mr. Zabinski presented his experience as Deputy Commissioner with vortex units followed by high-rate chlorination for the City of Yonkers, NY.

    chlorination. and as a result, constructed a second vortex facility at another location.

Presenter: Peter Moffa for Mark Boner, Vice President of Wet-Weather Environmental Technology Company

Topic: Columbus GA CSO chlorination-dechlorination and UV installations

On behalf of Mr. Boner, Mr. Moffa presented the full-scale wet-weather flow abatement technologies that have been tested in Columbus, GA, for flows up to 24 MGD. Two main treatment processes were constructed.

    and was simpler and less costly to operate. The filtration, UV process is currently offline and not in operation.

Session 3 Questions and answers

Q: What does "chlorine decay" mean and what causes it? What is the half-life?
A: Free chlorine reacts with organic material including bacteria and viruses and in the process of inhibiting the bacteria and viruses chlorine is consumed. Free chlorine also decays more rapidly in the presence of sunlight. The decay of TRC has been demonstrated in receiving waters and the laboratory. A first-order decay coefficient for TRC is generally estimated to be 2/day, which is equivalent to a half-life of approximately 8 hr.

Q: Bacteria reductions from the Rockland experience appear highly variable? What are the bacteria reductions associated with disinfection of wet-weather flows?
A: Fecal coliform densities in undisinfected CSO can range from hundreds of millions to hundreds of thousands units per 100 mL. Typical goals after disinfection are less than 1,000 units or less than 200 units per 100 mL. Bacteria reductions are presented in percent removal or log reductions. When presented in percent removals, the removals are generally greater than 99.99%. With respect to the Rockland data, disinfected densities ranged from 1 to 848 units per 100 mL. When considering that the undisinfected densities may have ranged up to millions of units, a range from 1 to 849 units in the effluent is not considered highly variable.

Q: How successful are CSO disinfection facilities?
A: Not knowing of all the facilities that may be disinfecting, it was estimated at the workshop to be in excess of 90%. Notwithstanding unusual flow circumstances and operational disruptions, if a disinfection facility is designed and operated correctly, it should be 100% effective.

Q: What were the phosphorous reductions in the Columbus GA experience?
A: The figure presented stated 60% phosphorus removal, which represents an annual removal by the vortex. An additional 10% was removed for the filter/UV train for a total of 70%.

Clarification: In Onondaga County's situation, most of the CSO phosphorus and ammonia will be treated at Metro because approximately 90% of the annual wet-weather flow will be stored and pumped back to Metro for treatment after the event.

Q: What is the volume stored in the interceptor system as compared to the original County alternative and full storage?
A: The existing Main Interceptor Sewer (MIS) collects the dry and wet-weather flow along the Onondaga Creek corridor. The total volume of the MIS itself is calculated as 3.9 MG. The MIS capacity is partly taken up by daily dry-weather flow (approximately one-third). During wet-weather flow the MIS fills completely to maximize flow to Metro and minimize CSO discharging to Onondaga Creek. For comparison purposes, the volume associated with the County's preferred alternative is 8.5 MG, which includes pipeline volume as well as the volume associated with the RTF. Similarly, the storage alternative is estimated at a total volume of 17 MG.

Clarification: Most importantly for Onondaga County is the fact that 90% of the total average annual CSO flow will be stored and conveyed for treatment at Metro leaving only 10% of the total left to be treated at the regional sites.

Q: What are the benefits of vortex compared to storage?
A: Storage does not provide immediate treatment of the larger storms as does vortex, but stores the entire storm volume. This volume is kept in the tank until the storm subsides and Metro can receive this volume. During this time floatables float and solids settle. Both floatables and solids need to be flushed from the tank after the storm. This requires specific flushing equipment.

Very large storms will exceed the storage volume and result in discharge from the storage tank. Any treatment within the tank is contingent upon time within the tank, which is dependent upon the rate of flow through the tank. Given equal treatment goals, storage tanks can treat floatables and solids at flow rates only one-quarter that of vortex beyond which turbulence prevents treatment. Conversely vortex continues to provide treatment up to 20 times that of storage.

In summary, vortex tanks:


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Susan Miller, Project Deputy Director
Phone 315-435-2260   Fax 315-435-5023
 Onondaga County Dept of Water Environment Protection